When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | N2O5_IUPAC(2004)_298K_210-410nm(rec).txt |
| NAME: | dinitrogen pentoxide |
| FORMULA: | N2O5 |
| AUTHOR(YEAR): | IUPAC(2004) |
| T: | 298K |
| λ: | 210-410nm(rec) |
| BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, and J. Troe, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phas reactions of Ox, HOx, NOx and SOx species",
Atmos. Chem. Phys. 4, 1461-1738 (2004);
DOI: 10.5194/acp-4-1461-2004
|
| COMMENTS: | IUPAC(2004) recommendation: 210-240 nm, mean of the data of F. Yao, I. Wilson, and H. Johnston, "Temperature-dependent ultraviolet absorption spectrum for dinitrogen pentoxide," J. Phys. Chem. 86, 3611-3615 (1982); DOI: 10.1021/j100215a023, and M.H. Harwood, J.B. Burkholder, and A.R. Ravishankara, "Photodissociation of BrONO2 and N2O5: Quantum yields for NO3 production at 248, 308, and 352.5 nm," J. Phys. Chem. A 102, 1309-1317 (1998); DOI: 10.1021/jp9729829, 240-410 nm, mean of the data of F. Yao, I. Wilson, and H. Johnston, "Temperature-dependent ultraviolet absorption spectrum for dinitrogen pentoxide," J. Phys. Chem. 86, 3611-3615 (1982); DOI: 10.1021/j100215a023, M.H. Harwood, R.L. Jones, R.A. Cox, E. Lutman, and O.V. Rattigan, "Temperature-dependent absorption cross sections of N2O5," J. Photochem. Photobiol. A 73, 167-175 (1993); DOI: 10.1016/1010-6030(93)90001-2, and M.H. Harwood, J.B. Burkholder, and A.R. Ravishankara, "Photodissociation of BrONO2 and N2O5: Quantum yields for NO3 production at 248, 308, and 352.5 nm," J. Phys. Chem. A 102, 1309-1317 (1998); DOI: 10.1021/jp9729829. The temperature dependence was parameterized: log10 σ(T) = log10 σ(298K)+ 1000B × (1/T - 1/298) and the corresponding temperature coefficients B derived (T = 233-313 K): -------------------
λ B
(nm) (K)
-------------------
260 -0.091
265 -0.100
270 -0.104
275 -0.112
280 -0.112
285 -0.126
290 -0.135
295 -0.152
300 -0.170
305 -0.194
310 -0.226
315 -0.253
320 -0.294
325 -0.338
330 -0.388
335 -0.409
340 -0.492
345 -0.530
350 -0.583
355 -0.719
360 -0.770
365 -0.801
370 -0.885
375 -0.765
380 -0.992
385 -0.992
390 -0.949
395 -0.845
400 -0.966
405 -1.00
410 -1.16 |
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